DEFORMATION OF OCTAHEDRA AT LAB6(100) SURFACE STUDIED BY HREELS

被引:18
|
作者
NAGAO, T [1 ]
KITAMURA, T [1 ]
IIZUKA, T [1 ]
UMEUCHI, M [1 ]
OSHIMA, C [1 ]
OTANI, S [1 ]
机构
[1] NATL INST RES INORGAN MAT,TSUKUBA,IBARAKI 305,JAPAN
关键词
10;
D O I
10.1016/0039-6028(93)90809-X
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The surface phonons of LaB6(100) surface have been investigated by means of high resolution electron energy spectroscopy. On the clean surface we have observed 8 loss peaks in the off-specular spectra, of which the higher energy losses are related to the vibrations of the three-dimensional network of boron. Theoretical analysis based on a force constant model strongly suggests the deformation of the three-dimensional network of boron; the topmost octahedra are expanded by approximately 0.004 nm parallel to the surface.
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页码:391 / 395
页数:5
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