SEMI-CLASSICAL SELF-CONSISTENT FIELD (SC SCF) APPROXIMATION FOR EIGENVALUES OF COUPLED-VIBRATION SYSTEMS

被引：241

作者：

GERBER, RB ^{[1
]}

RATNER, MA ^{[1
]}

机构：

[1] HEBREW UNIV JERUSALEM,INST ADV STUDIES,JERUSALEM 91000,ISRAEL

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 68卷 / 01期

关键词：

D O I：

10.1016/0009-2614(79)80099-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The self-consistent-field (SCF) approximation for coupled-vibron systems in the semiclassical limit yields Hartree-type equations, in which only the eigenenergies and turning points are self-consistently evaluated. Calculations yield vibrational energies in excellent agreement with quantum SCF and exact quantum results. Applications and extensions are briefly discussed. © 1979.

引用

页码：195 / 198

页数：4

共 19 条

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