Separation of Transuranium and Transplutonium Elements on S-957 Sorbent

被引：4

作者：

Nekrasova, N. A. ^{[1
]}

Shumilova, Yu. V. ^{[1
]}

Milyutin, V. V. ^{[1
]}

Gelis, V. M. ^{[1
]}

Logunov, M. V. ^{[2
]}

Lyzlova, E. V. ^{[2
]}

Glukhova, A. V. ^{[2
]}

机构：

[1] Russian Acad Sci, Frumkin Inst Phys Chem & Electrochem, Leninskii Pr 31,Block 4, Moscow 119991, Russia

[2] Mayak Prod Assoc, Fed State Unitary Enterprise, Ozersk, Chelyabinsk Obl, Russia

来源：

RADIOCHEMISTRY | 2011年 / 53卷 / 04期

关键词：

sorption; column chromatography; transuranium elements; transplutonium elements;

D O I：

10.1134/S1066362211040096

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Sorption of Pu4+, UO22+, NpO2+, Am3+, and Eu3+ ions on S-957 cation exchanger from 2-7 M HNO3 solutions was studied. The following selectivity series was obtained: Pu4+ > UO22+ > NpO2+ > Am3+ approximate to Eu3+. The static and dynamic capacities of the sorbent for Pu were determined, and the eluent composition for the efficient desorption was chosen. The possibility of separating Pu(IV)-Am(III) and Pu(IV)-Np(V) pairs on the sorbent in the column chromatography mode was demonstrated.

引用

页码：393 / 395

页数：3