RADICAL COPOLYMERIZATION OF 2-ACRYLOYL THIOXANTHONE WITH METHYL-METHACRYLATE

被引：15
|
作者：
CATALINA, F [1 ]
PEINADO, C [1 ]
MADRUGA, EL [1 ]
SASTRE, R [1 ]
MATEO, JL [1 ]
机构：
[1] MANCHESTER POLYTECH,DEPT CHEM,MANCHESTER M1 5GD,LANCS,ENGLAND
来源：
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 1990年 / 28卷 / 05期
关键词：
D O I：
10.1002/pola.1990.080280502
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A novel monomer, 2‐acryloyl thioxanthone (TXA), was prepared by reaction of 2‐hydroxy thioxanthone with acryloyl chloride. Copolymerization of TXA with methyl methacrylate (MMA) in DMF at 80°C was studied in order to evaluate relative reactivities of these monomers. Values of 1.36 and 0.5 were found for the respective reactivity ratios of MMA and TXA, respectively. The resonance stabilization and polar properties were determined and discussed in terms of spectroscopic data. Copyright © 1990 John Wiley & Sons, Inc.
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收藏
页码：967 / 972
页数：6
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