MASS SPECTRA AND STABILITY OF DIAROMATIC-CHROMIUM COMPLEXES

被引：30

作者：

HERBERIC.GE

MULLER, J

机构：

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1969年 / 16卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(00)81641-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The mass spectra of some dibenzenechromium derivatives {Cr(C6H6)2, Cr[1,3,5-(CH3)3C6H3]2 ,Cr(C6H6)(C6H5C6 H5), and Cr(C6H5C6H5)2} are reported. The fragment formation proceeds almost exclusively by successive elimination of the ring ligands. Ionisation potentials as well as appearance potentials were measured and were used to calculate dissociation energies and total bonding energies for the gaseous cations and the neutral complexes. The following stability sequence is established for the metalligand bond strength in the neutral complexes: {A figure is presented}. © 1969.

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页码：111 / &

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共 16 条

[1] HEATS OF COMBUSTION AND FORMATION OF BIS-BENZENECHROMIUM [J].

FISCHER, AK ;

COTTON, FA ;

WILKINSON, G .

JOURNAL OF PHYSICAL CHEMISTRY, 1959, 63 (02) :154-155

[2] UBER AROMATENKOMPLEXE VON METALLEN .42. BILDUNGSWARMEN VON DI-MESITYLEN-CHROM(O) UND DI-PSEUDOCUMOL-CHROM(O) [J].

FISCHER, EO ;

SCHREINER, S ;

RECKZIEGEL, A .

CHEMISCHE BERICHTE-RECUEIL, 1961, 94 (01) :258-262

[3] UBER AROMATENKOMPLEXE VON METALLEN .6. ZUR FRAGE DER STRUKTUR DER CHROM-PHENYL-VERBINDUNGEN [J].

FISCHER, EO ;

SEUS, D .

CHEMISCHE BERICHTE-RECUEIL, 1956, 89 (08) :1809-1815

[4] UBER AROMATENKOMPLEXE VON METALLEN .47. BILDUNGSWARMEN VON DI-BENZOL-MOLYBDAN(0) UND DI-BENZOL-VANADIN(0) [J].

FISCHER, EO ;

RECKZIEGEL, A .

CHEMISCHE BERICHTE-RECUEIL, 1961, 94 (08) :2204-2208

[5] UBER AROMATENKOMPLEXE VON METALLEN .3. ZUR DARSTELLUNG DES DI-BENZOL-CHROMS [J].

FISCHER, EO ;

HAFNER, W .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1956, 286 (3-4) :146-148

[6]

FURLANI C, 1958, RIC SCI, V28, P973

[7] NEUE BEITRAGE ZUR KENNTNIS DES TRIPHENYLCHROMS BZW BENZOLBIPHENYLCHROMS [J].

HEIN, F ;

KLEINERT, P ;

KURRAS, E .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1957, 289 (5-6) :229-243

[8] UBER AROMATENKOMPLEXE VON METALLEN .82. ZUR LADUNGSVERTEILUNG IN DIAROMATEN-CHROM(0)-KOMPLEXEN UND UBER DIE FRIEDEL-CRAFTS-ISOMERISIERUNG BEI DER SYNTHESE VON DIMESITYLENCHROM(0) [J].

HUTTNER, G ;

FISCHER, EO ;

ELSCHENB.C .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1965, 3 (04) :330-&

[9] MASS SPECTROSCOPY OF TRANSITION METAL PI-COMPLEXES WITH 5 6 AND 7 MEMBERED AROMATIC RING LIGANDS [J].

MULLER, J ;

GOSER, P .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1968, 12 (01) :163-+

[10] MASSENSPEKTROMETRISCHE UNTERSUCHUNGEN AN DICYCLOPENTADIENYLKOMPLEXEN VON UBERGANGSMETALLEN [J].

MULLER, J ;

DOR, L .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1967, 10 (02) :313-&