ELECTROCHEMICAL-BEHAVIOR OF 6-(N,N-DIMETHYL-AMINO)FULVENE IN APROTIC MEDIA

被引：0
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作者：
SHIROKII, VL
YAROSH, MV
KONOVALOVA, TP
RYABTSEV, AN
MAIER, NA
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来源：
SOVIET ELECTROCHEMISTRY | 1992年 / 28卷 / 07期
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中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Cyclic voltammetry (CVA) was used to study the electroreduction of 6-(N,N-dimethylamino)fulvene (fulvene I) in aprotic polar solvents (acetonitrile, DMSO, DMF). It was shown that in solutions with tetraethylammonium perchlorate, fulvene I is irreversibly reduced by adding one electron and forming radical-anions subsequently dimerizing and undergoing further chemical transformations. The reaction products of the fulvene I radical-anions are electrochemically active and can be recorded by CVA. The electroreduction mechanism of fulvene I was discussed.
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页码：853 / 855
页数：3
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