STATISTICAL-MECHANICS BASIS OF MACLEODS FORMULA

被引：30

作者：

BOUDHHIR, ME ^{[1
]}

MANSOORI, GA ^{[1
]}

机构：

[1] UNIV ILLINOIS,DEPT CHEM ENGN,BOX 4348,CHICAGO,IL 60680

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1990年 / 94卷 / 21期

关键词：

D O I：

10.1021/j100384a068

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this work the theoretical basis for the famous formula of Macleod, relating the surface tension of a liquid in equilibrium with its own vapor to the one-particle densities in the two phases of the system, is derived. Using the statistical-mechanical definition of the surface tension, it is proved that this property is, at the first approximation, given by the Macleod formula. © 1990 American Chemical Society.

引用

页码：8362 / 8364

页数：3

共 15 条

[1] [Anonymous], 1982, MOL THEORY CAPILLARI
[2] A tentative statistical theory of Macleod's equation for surface tension, and the parachor
Fowler, RH
[J]. PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1937, 159 (A897) : 0229 - 0246
[3] SURFACE-TENSION OF A MOLECULAR FLUID MANY-BODY POTENTIAL
GRANT, M
DESAI, RC
[J]. MOLECULAR PHYSICS, 1981, 43 (05) : 1035 - 1041
[4] A GENERAL KINETIC THEORY OF LIQUIDS .2. EQUILIBRIUM PROPERTIES
GREEN, HS
[J]. PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1947, 189 (1016): : 103 - 117
[5] GREEN HS, 1969, MOL THEORY FLUIDS, P194
[6] SURFACE-TENSION COMPRESSIBILITY RELATION
HENDERSON, JR
[J]. MOLECULAR PHYSICS, 1980, 39 (03) : 709 - 714
[7] SURFACE-TENSION - A SIMPLE CORRELATION FOR NATURAL-GAS + CONDENSATE SYSTEMS
HUGILL, JA
VANWELSENES, AJ
[J]. FLUID PHASE EQUILIBRIA, 1986, 29 : 383 - 390
[8] STATISTICAL THERMODYNAMICS OF NONUNIFORM FLUIDS
LEBOWITZ, JL
PERCUS, JK
[J]. JOURNAL OF MATHEMATICAL PHYSICS, 1963, 4 (01) : 116 - &
[9] GENERALIZED VANDERWAALS THEORIES FOR SURFACE-TENSION AND INTERFACIAL WIDTH
LOVETT, R
DEHAVEN, PW
VIECELI, JJ
BUFF, FP
[J]. JOURNAL OF CHEMICAL PHYSICS, 1973, 58 (05) : 1880 - 1885
[10] On a relation between surface tension and density
Macleod, DB
[J]. TRANSACTIONS OF THE FARADAY SOCIETY, 1923, 19 (01): : 0038 - 0041

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