ETA-4-BENZOCYCLOBUTADIENE-ETA-5-CYCLOPENTADIENYLCOBALT, A NEW AROMATIC SANDWICH COMPLEX

被引：15
|
作者：
DUCLOS, RI [1 ]
VOLLHARDT, KPC [1 ]
YEE, LS [1 ]
机构：
[1] UNIV CALIF BERKELEY,DEPT CHEM,BERKELEY,CA 94720
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 174卷 / 01期
基金：
美国国家科学基金会;
关键词：
D O I：
10.1016/S0022-328X(00)96167-9
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reaction of 1,8-bis(trimethylsilyl)-cis-cis-3,5-octadiene-1,7-diyne with CpCo(CO)2 gives η4-1,2-bis(trimethylsilyl)benzocyclobutadiene-η5-cyclopentadienylcobalt. Desilylation with fluoride results in the parent compound, the first known benzocyclobutadiene sandwich complex. NMR analysis provides evidence for diatropic character of the complexed as opposed to the free ligand. © 1979.
引用
收藏
页码：109 / 114
页数：6
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