Heat transfer and the continuous production of hydroxypropyl starch in a static mixer reactor

被引:14
作者
Lammers, Gerard [1 ]
Beenackers, Antonie A. C. M. [1 ]
机构
[1] Univ Groningen, Dept Chem Engn, NL-9747 AG Groningen, Netherlands
关键词
Catalysis - Catalysts - Heat transfer - Hydrolysis - Mathematical models - Mixers (machinery) - Oxides - Solutions - Starch - Thermal gradients;
D O I
10.1016/0009-2509(94)00292-4
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
A novel continuous reactor for the chemical derivation of aqueous starch solutions based on static mixers is proposed. Both the experimentally observed axial and radial temperature gradients in the static mixer could be accurately described by a pseudohomogeneous two-dimensional heat transfer (PTHT) model. Hydroxypropyl starch was produced by reacting propylene oxide with an aqueous solution of potato starch. The hydroxide acted as a catalyst. The observed conversions of propylene oxide are in excellent agreement with model prediction based on both a one-dimensional and a two-dimensional plug flow reactor model.
引用
收藏
页码:5097 / 5107
页数:11
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