QUADRUPOLE EFFECTS IN CROWN-ETHER SALT COMPLEXES - A SOLID-STATE NMR-STUDY

被引：20
|
作者：
PIETRASS, T [1 ]
BURKERT, PK [1 ]
机构：
[1] TECH UNIV MUNICH,INST ANORGAN CHEM,LICHTENBERGSTR 4,W-8046 GARCHING,GERMANY
来源：
MAGNETIC RESONANCE IN CHEMISTRY | 1993年 / 31卷 / 08期
关键词：
LI-7; NA-23 AND C-13 SOLID-STATE NMR SPECTROSCOPY; QUADRUPOLAR INTERACTION; MAGIC ANGLE; SPINNING; CROWN; ETHER SALT COMPLEXES;
D O I：
10.1002/mrc.1260310804
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Li-7, Na-23 and C-13 solid-state NMR spectroscopy under static and magic angle spinning conditions was used to study the salt complexes of lithium chloride, lithium bromide, lithium perchlorate and lithium nitrate with 12-crown-4 and of sodium nitrate with 15-crown-5. Structural and dynamic features of the compounds are discussed, focusing on the quadrupolar interaction and temperature-dependent phenomena.
引用
收藏
页码：709 / 713
页数：5
相关论文
共 50 条
  • [41] A SOLID-STATE NMR-STUDY ON CRYSTALLINE FORMS OF NYLON-6
    OKADA, A
    KAWASUMI, M
    TAJIMA, I
    KURAUCHI, T
    KAMIGAITO, O
    JOURNAL OF APPLIED POLYMER SCIENCE, 1989, 37 (05) : 1363 - 1371
  • [42] C-13 SOLID-STATE NMR-STUDY OF POLYACENIC MATERIALS
    YAMABE, T
    YAMANAKA, S
    TANAKA, K
    TERAO, T
    MAEDA, S
    YATA, S
    PHYSICAL REVIEW B, 1988, 37 (10): : 5808 - 5810
  • [43] NMR-STUDY OF SOLID-STATE REACTION IN CO-SN MULTILAYERS
    JEDRYKA, E
    PANISSOD, P
    GUILMIN, P
    MARCHAL, G
    HYPERFINE INTERACTIONS, 1989, 51 (1-4): : 1103 - 1110
  • [44] N-15 SOLID-STATE NMR-STUDY OF LIGANDS IN PLATINUM MIXED-VALENCE COMPLEXES
    AUSTIN, EJW
    BARRIE, PJ
    CLARK, RJH
    INORGANIC CHEMISTRY, 1992, 31 (21) : 4281 - 4285
  • [45] THEORETICAL-STUDY OF CHEMICAL INTERACTIONS IN CROWN-ETHER CATION COMPLEXES
    HATAUE, I
    OISHI, Y
    KUBOTA, M
    FUJIMOTO, H
    TETRAHEDRON, 1991, 47 (45) : 9317 - 9328
  • [46] AN NMR-STUDY OF STRUCTURE AND DYNAMICS OF POLY(FUMARATE)S IN THE SOLID-STATE
    KUROSU, H
    YAMADA, T
    ANDO, I
    SATO, K
    OTSU, T
    JOURNAL OF MOLECULAR STRUCTURE, 1993, 300 : 303 - 311
  • [47] Preparation, solid-state characterization, and computational study of a crown ether attached to a squaramide
    Frontera, A
    Orell, M
    Garau, C
    Quiñonero, D
    Molins, E
    Mata, I
    Morey, J
    ORGANIC LETTERS, 2005, 7 (08) : 1437 - 1440
  • [48] A SOLID-STATE TI-205 NMR-STUDY OF THE TL+-LASALOCID AND TL+-GRAMICIDIN COMPLEXES
    HINTON, JF
    METZ, KR
    TURNER, GL
    BENNETT, DL
    MILLETT, FS
    JOURNAL OF MAGNETIC RESONANCE, 1985, 64 (01) : 120 - 123
  • [49] SOLID-STATE P-31 CP-MAS NMR-STUDY OF PHOSPHINE COMPLEXES OF MERCURY(II)
    ALLMAN, T
    LENKINSKI, RE
    INORGANIC CHEMISTRY, 1986, 25 (18) : 3202 - 3204
  • [50] SYNTHESIS AND H-1-NMR COMPLEXATION STUDIES OF ALKALIMETAL BITHIOXANTHYLIDENE CROWN-ETHER COMPLEXES
    SCHOEVAARS, AM
    HULST, R
    FERINGA, BL
    TETRAHEDRON LETTERS, 1994, 35 (52) : 9745 - 9748
12345