Bis(acetato-kappa O)bis(4,5-dimethylbenzene-1,2-diamine-kappa N)zinc

被引：3
作者：
Geiger, David K. [1 ]
机构：
[1] State Univ New York Coll Geneseo, Dept Chem, 1 Coll Circle, Geneseo, NY 14454 USA
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷
关键词：
data-to-parameter ratio = 13.2; mean σ(C-C) = 0.004 Å; R factor = 0.036; single-crystal X-ray study; T = 200 K; wR factor = 0.094;
D O I：
10.1107/S160053681203036X
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The structure of the title compound, [Zn(CH3COO)(2)(C8H12N2)(2)], has one half molecule in the asymmetric unit. The Zn-II atom is situated on a twofold rotation axis and is tetrahedrally coordinated by two N and two O atoms. The crystal packing displays intermolecular N-H center dot center dot center dot O hydrogen bonds and intramolecular N-H center dot center dot center dot O and N-H center dot center dot center dot N hydrogen bonding.
引用
收藏
页码：M1040 / +
页数：7
相关论文
共 12 条
  • [1] [Anonymous], 2009, SAINT
  • [2] [Anonymous], 2010, APEX2
  • [3] Bruker, 2004, XSHELL
  • [4] Geometry of metal-ligand interactions in proteins
    Harding, MM
    [J]. ACTA CRYSTALLOGRAPHICA SECTION D-BIOLOGICAL CRYSTALLOGRAPHY, 2001, 57 : 401 - 411
  • [5] Mercury CSD 2.0 -: new features for the visualization and investigation of crystal structures
    Macrae, Clare F.
    Bruno, Ian J.
    Chisholm, James A.
    Edgington, Paul R.
    McCabe, Patrick
    Pidcock, Elna
    Rodriguez-Monge, Lucia
    Taylor, Robin
    van de Streek, Jacco
    Wood, Peter A.
    [J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2008, 41 : 466 - 470
  • [6] Coordination Dynamics of Zinc in Proteins
    Maret, Wolfgang
    Li, Yuan
    [J]. CHEMICAL REVIEWS, 2009, 109 (10) : 4682 - 4707
  • [7] Synthesis and crystal structure of (o-Diaminobenzene)2 Zn(OAc)2
    Mei, L.
    Li, J.
    Ming, Z. S.
    Rong, L. Q.
    Liang, L. X.
    [J]. RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2009, 35 (12) : 871 - 873
  • [8] Synthetic analogues relevant to the structure and function of zinc enzymes
    Parkin, G
    [J]. CHEMICAL REVIEWS, 2004, 104 (02) : 699 - 767
  • [9] Sheldrick G.M., 2008, SADABS
  • [10] A short history of SHELX
    Sheldrick, George M.
    [J]. ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 : 112 - 122
12