X-RAY K EMISSION-SPECTRA OF VANADIUM IN VARIOUS OXIDATION-STATES

被引：23

作者：

YASUDA, S

KAKIYAMA, H

机构：

[1] National Industrial Research Institute of Kyushu, Tosu, Saga

来源：

X-RAY SPECTROMETRY | 1978年 / 7卷 / 01期

关键词：

D O I：

10.1002/xrs.1300070108

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The Kα1,2, Kβ1,3, Kβ5, and Kβ″ emission spectra of vanadium in the element and several V (III), V(IV), and V(V) compounds have been measured with a two‐crystal X‐ray spectrometer. The Kα1 and Kβ1,3 peaks shift slightly to lower energies with increasing lthe oxidation state of vanadium atom and the Kβ5 peak shifts to higher with it. An approximately linear relationship between Kα1 width and Kα1/Kα2 intensity ratio can be used for lindentification of vanadium oxidation state. Copyright © 1978 Heyden & Son Ltd

引用

页码：23 / 25

页数：3

共 10 条

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