PHENOL OXIDATION AND BIOSYNTHESIS .27. REACTIONS OF RELEVANCE TO THE FORMATION OF ERYSODIENONE INVITRO

被引：9

作者：

BARRETT, AGM ^{[1
]}

BARTON, DHR ^{[1
]}

FRANCKOWIAK, G ^{[1
]}

PAPAIOANNOU, D ^{[1
]}

WIDDOWSON, DA ^{[1
]}

机构：

[1] UNIV LONDON IMPERIAL COLL SCI & TECHNOL,DEPT CHEM,LONDON SW7 2AY,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1979年 / 03期

关键词：

D O I：

10.1039/p19790000662

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Potassium hexacyanoferrate(III) oxidation of N-(2-arylethyl)-2- arylacetamide and arylmethyl arylpropyl ketone gave the corresponding nine-membered ring derivatives formed by p,p-phenol oxidative coupling (where aryl was 3-hydroxy-4-methoxyphenyl). This strongly supports the previously reported mechanism for the in vitro formation of erysodienone. The required ketone was prepared from O-benzylisovanillin by homologation with toluene-4-sulphonylmethyl isonitrile.

引用

页码：662 / 668

页数：7

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