SYNTHESIS, X-RAY-ANALYSIS, AND ELECTROCHEMICAL STUDY OF SOME MANGANESE CARBONYL DERIVATIVES WITH 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE, DPPFE

被引：11
|
作者：
ONAKA, S
HAGA, MA
TAKAGI, S
OTSUKA, M
MIZUNO, K
机构：
[1] NAGOYA INST TECHNOL, DEPT APPL CHEM, SHOWA KU, NAGOYA, AICHI 466, JAPAN
[2] MIE UNIV, FAC EDUC, DEPT CHEM, TSU, MIE 514, JAPAN
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1994年 / 67卷 / 09期
关键词：
D O I：
10.1246/bcsj.67.2440
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Synthesis and X-ray structure analyses were carried out for fac-cis-[MnCl(CO)3dppfe] and fac-cis-[MnH-(CO)3dppfe], and a cyclic voltammetric study was made for a series of manganese carbonyl derivatives with 1,1'-bis(diphenylphosphino)ferrocene (dppfe), including these new compounds. Unusually a low oxidation potential for the Mn site is revealed for [Mn(MeCp)(CO)dppfe]. A good correlation between nu(CO) and the oxidation potential for the Mn atom has been clarified.
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收藏
页码：2440 / 2446
页数：7
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