SYNTHESIS, X-RAY-ANALYSIS, AND ELECTROCHEMICAL STUDY OF SOME MANGANESE CARBONYL DERIVATIVES WITH 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE, DPPFE

被引：11

作者：

ONAKA, S

HAGA, MA

TAKAGI, S

OTSUKA, M

MIZUNO, K

机构：

[1] NAGOYA INST TECHNOL, DEPT APPL CHEM, SHOWA KU, NAGOYA, AICHI 466, JAPAN

[2] MIE UNIV, FAC EDUC, DEPT CHEM, TSU, MIE 514, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1994年 / 67卷 / 09期

关键词：

D O I：

10.1246/bcsj.67.2440

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Synthesis and X-ray structure analyses were carried out for fac-cis-[MnCl(CO)3dppfe] and fac-cis-[MnH-(CO)3dppfe], and a cyclic voltammetric study was made for a series of manganese carbonyl derivatives with 1,1'-bis(diphenylphosphino)ferrocene (dppfe), including these new compounds. Unusually a low oxidation potential for the Mn site is revealed for [Mn(MeCp)(CO)dppfe]. A good correlation between nu(CO) and the oxidation potential for the Mn atom has been clarified.

引用

页码：2440 / 2446

页数：7

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