[2-(1-{2-[Azanidyl(ethylsulfanyl)methylidene-kappa N]hydrazin-1-ylidene-kappa N-1}ethyl)phenolato-kappa O](pyridine-kappa N)nickel(II)

被引：3

作者：

Takjoo, Reza ^{[1
]}

Ng, Seik Weng ^{[2
,3
,4
]}

Tiekink, Edward R. T. ^{[2
]}

机构：

[1] Ferdowsi Univ Mashhad, Sch Sci, Dept Chem, Mashhad 917751436, Iran

[2] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia

[3] King Abdulaziz Univ, Chem Dept, Jeddah, Saudi Arabia

[4] King Abdulaziz Univ, Fac Sci, Jeddah, Saudi Arabia

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷

关键词：

D O I：

10.1107/S1600536812026177

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The Ni-II atom in the title complex, [Ni(C11H13N3OS)(C5H5N)], exists within a square-planar N3O donor set provided by N,N ',O atoms of the dianionic tridentate ligand and a pyridine N atom. The maximum deviation from the ideal geometry is seen in the N-Ni-N five-membered chelate bite angle of 83.28 (12)degrees. The pyridine molecule forms a dihedral angle of 44.43 (6)degrees with the N3O donor set.Supramolecular stacks along the a axis mediated by alternating pi-pi interactions between the pyridine and five-[centroid-centroid distance = 3.4784 (16) angstrom] and six-membered[3.4633 (17) angstrom] chelate rings, feature in the crystal packing.

引用

页码：M911 / +

页数：9

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