KIRKWOOD-SALSBURG INTEGRAL EQUATION AND VIRIAL COEFFICIENTS OF LENNARD-JONES MOLECULES

被引:2
作者
CHUNG, HS
机构
[1] Central Research Division Laboratory, Mobil Research and Development Corporation, Princeton
关键词
D O I
10.1080/00268976900100621
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The fifth virial coefficients Ec and Ep are derived for a classical fluid composed of molecules interacting according to the Lennard-Jones potential. The calculations are based on the Kirkwood-Salsburg integral equation and the superposition approximation. It is found that, unlike the systems considered in a previous communication, satisfactory agreement between the present results and the known values is possible only at high temperatures. © 1969, Taylor & Francis Group, LLC. All rights reserved.
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页码:553 / &
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