ALDOL CONDENSATION CATALYZED BY HIGHLY ELECTRON-DEFICIENT IRON PORPHYRIN

被引：9

作者：

KURODA, Y

SUZUKI, Y

OGOSHI, H

机构：

[1] Department of Synthetic Chemistry, Kyoto University, Yoshida, Sakyo-ku, Kyoto

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 05期

关键词：

PORPHYRIN; ALDOL CONDENSATION; CATALYSIS; REDOX POTENTIAL;

D O I：

10.1016/S0040-4039(00)75807-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The perchlorate complex of 2, 4, 6, 8-tetratrifluoromethyl-1, 3, 5, 7-tetraethylporphyrin.Fe(III) shows the extraordinarily positive reduction potential, 0.81 V vs. Ag/AgCl (reversible). The complex catalyzes the aldol condensation of cyclohexanone.

引用

页码：749 / 750

页数：2

共 6 条

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