CYANOPHOSPHORUS COMPOUNDS .3. STRUCTURE OF THE DICYANOPHOSPHIDE ION IN A CROWN-ETHER SODIUM-SALT

被引：42

作者：

SHELDRICK, WS ^{[1
]}

KRONER, J ^{[1
]}

ZWASCHKA, F ^{[1
]}

SCHMIDPETER, A ^{[1
]}

机构：

[1] UNIV MUNICH,INST ANORGAN CHEM,D-8000 MUNICH 2,FED REP GER

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 12期

关键词：

D O I：

10.1002/anie.197909341

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Comparably large positively and negatively charged structural units are present in the lattice of the 1:1:1: complex of NaP(CN)2, [18]crown‐6, and tetrahydrofuran: Na+/crown ether/2 THF and Na+/crown ether/2P(CN) 2−. The P(CN) 2− ion is planar and bent; the calculated structure is essentially confirmed by X‐ray structure analysis. P/CN interaction is slight. Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：934 / 935

页数：2