5-(4-Fluorophenyl)-3-[5-methyl-1-(4-methylphenyl)-1H- 1,2,3-triazol-4-yl]-N-phenyl-4,5-dihydro-1H-pyrazole-1-carbothioamide

In the title compound, C26H23FN6S, the pyrazole ring has an envelope conformation, with the methine C atom being the flap atom. The thiourea group is close to being coplanar with the pyrazole N atoms [N-N-C-S torsion angle = 176.78 (15)degrees], which allows for an intramolecular N-H center dot center dot center dot N hydrogen bond; the connected triazole ring is nearly coplanar with this ring [N-C-C-N = -172.65 (19)degrees]. There is a significant twist between the pyrazole ring and attached fluorobenzene ring [N-C-C-C = -18.8 (3)degrees] and a greater twist between triazole and attached tolyl ring [dihedral angle = 58.25 (14)degrees]. In the crystal, supramolecular chains aligned along [40,10] are consolidated by pi-pi interactions between the triazole and phenyl rings [centroid-centroid distance = 3.7053 (13) angstrom].