A NEW INORGANIC METALLOCYCLE CONTAINING TIN, SULFUR, PHOSPHORUS AND NITROGEN - CRYSTAL AND MOLECULAR-STRUCTURE OF SPIROBICYCLIC ME2SN(SPPH2NPPH2S)2

被引：66
作者：
HAIDUC, I [1 ]
SILVESTRU, C [1 ]
ROESKY, HW [1 ]
SCHMIDT, HG [1 ]
NOLTEMEYER, M [1 ]
机构：
[1] UNIV GOTTINGEN,INST ANORGAN CHEM,W-3400 GOTTINGEN,GERMANY
来源：
POLYHEDRON | 1993年 / 12卷 / 01期
关键词：
D O I：
10.1016/S0277-5387(00)87055-2
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new inorganic heterocycle is obtained by reacting potassium tetraphenyldithio-imidodiphosphinate with trimethyltin and dimethyltin chlorides, in benzene. X-ray diffraction analysis reveals a spirocyclic structure with the dimethyltin moiety as the coordination centre with non-planar six-membered SnS2P2N rings. The coordination at tin is nearly perfectly octahedral, with equal Sn-S [273.3(2) and 273.7(2) pm] and P-S bonds [200.9(3) and 201.9(3) pm]. The S-Sn-S and H3C-Sn-CH3 units are co-linear.
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页码：69 / 75
页数：7
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