THERMAL-DIFFUSION FACTOR IN GAS-MIXTURES AND DUFOUR EFFECT

被引：0

作者：

MAGHARI, A ^{[1
]}

BORDBAR, A ^{[1
]}

BOUSHEHRI, A ^{[1
]}

机构：

[1] SHIRAZ UNIV,DEPT CHEM,SHIRAZ,IRAN

来源：

INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 1993年 / 32卷 / 05期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new formula for thermal diffusion factor, alpha(T), is presented on the basis of thermodynamics of irreversible processes. By using the virial equation of state, the nonideality effects are considered, and the pressure dependence of diffusion thermoeffect is interpreted from the theoretical results. Furthermore, by a modified apparatus, a study of the Dufour effect is made for three different gas mixtures: H-2/C2H4, H-2/C2H2 and H-2/NO for which the Dufour effect have not been measured earlier. The value of the thermal diffusion factor are evaluated for the above mixtures according to the obtained formula.

引用

页码：414 / 417

页数：4