DEHYDRATION OF WATER-PYRIDINE MIXTURE THROUGH POLY(ACRYLONITRILE-CO-ACRYLIC ACID) MEMBRANE BY PERVAPORATION

被引:26
作者
LEE, YM
OH, BK
机构
[1] Department of Industrial Chemistry, College of Engineering, Hanyang University, Seoul
关键词
PERVAPORATION; IN SITU COMPLEXATION; CATALYTIC TRANSPORT;
D O I
10.1016/0376-7388(94)00170-4
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
An aqueous pyridine solution was dehydrated by using modified polyacrylonitrile membranes to form in situ complexes with the solute in the feed solution, The pervaporation separation of a water-pyridine mixture using poly(acrylonitrile-co-acrylic acid) membranes exhibited a separation factor ranging from 13.4 to 2207 and a flux of 45-610 g/m(2) h depending on the operating temperature and the concentration of the feed mixture. The permeation mechanism through the membrane is explained on the basis of the molecular interaction between the permeants and the membrane.
引用
收藏
页码:183 / 189
页数:7
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