A STUDY OF NICKLE ION EXTRACTED ELECTROCHEMICALLY BY 2,2-BIPYRIDINE AT THE WATER/NITROBENZENE INTERFACE

被引:2
|
作者
Liu Yuqing [1 ]
Wang Erkang [1 ]
机构
[1] Chinese Acad Sci, Chungchun Inst Appl Chem, Beijing 100864, Peoples R China
关键词
D O I
10.3866/PKU.WHXB19880517
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Transfer behavior of nickle ion extracted electrochemically by 2,2'-bipyridine at the water/nitrobenzene interface has been investigated by cyclic voltammetry. The preceding or following chemical reaction was coupled to the electrolytic transfer process,respectively. The extracted species are successive complexes between Ni( II) and 2,2'-bipyridine An irreversible phenomenon similar to that observed at the metal electrode/electrolyte solution interface was observed directly. Voltammetric behaviors with coupled chemical reactions have been discussed.
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页码:527 / 530
页数:4
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