TOTAL SYNTHESIS OF ALL 8 STEREOISOMERS OF ALPHA-TOCOPHERYL ACETATE - DETERMINATION OF THEIR DIASTEREOISOMERIC AND ENANTIOMERIC PURITY BY GAS-CHROMATOGRAPHY

被引：73
作者：
COHEN, N
SCOTT, CG
NEUKOM, C
LOPRESTI, RJ
WEBER, G
SAUCY, G
机构：
来源：
HELVETICA CHIMICA ACTA | 1981年 / 64卷 / 04期
关键词：
D O I：
10.1002/hlca.19810640422
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
引用
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页码：1158 / 1173
页数：16
相关论文
共 27 条
[1]   TOTAL SYNTHESIS OF NATURAL ALPHA-TOCOPHEROL .4. PREPARATION OF CHROMANE RING-SYSTEM FROM TRIMETHYLHYDROQUINONE AND OPTICALLY-ACTIVE C-4 AND C5 SYNTHONE [J].
BARNER, R ;
SCHMID, M .
HELVETICA CHIMICA ACTA, 1979, 62 (07) :2384-2399
[2]   DETERMINATION OF THE ENANTIOMERIC PURITY OF ALPHA-TOCOPHEROL BY C-13 NMR-SPECTROSCOPY [J].
BREMSER, W ;
VOGEL, FGM .
ORGANIC MAGNETIC RESONANCE, 1980, 14 (02) :155-156
[3]   BASIC BEHAVIOR OF EPOXIDES IN PRESENCE OF HALIDE IONS .2. DEHYDROHALOGENATION OF PHOSPHONIUM HALIDES BY EPOXIDES .1. FORMATION OF YLIDES AND REACTION WITH CARBONYL-COMPOUNDS [J].
BUDDRUS, J .
CHEMISCHE BERICHTE-RECUEIL, 1974, 107 (06) :2050-2061
[4]   CAROTENOIDS AND RELATED COMPOUNDS .14. STEREOCHEMISTRY AND SYNTHESIS OF GERANIOL NEROL FARNESOL AND PHYTOL [J].
BURRELL, JWK ;
GARWOOD, RF ;
JACKMAN, LM ;
OSKAY, E ;
WEEDON, BCL .
JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1966, (23) :2144-+
[5]   THE REACTION OF THIONYL CHLORIDE WITH ALLYLIC ALCOHOLS [J].
CASERIO, FF ;
DENNIS, GE ;
DEWOLFE, RH ;
YOUNG, WG .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1955, 77 (15) :4182-4183
[6]   SYNTHETIC STUDIES ON (2R,4'R,8'R)-ALPHA-TOCOPHEROL FACILE SYNTHESES OF OPTICALLY-ACTIVE, SATURATED, ACYCLIC ISOPRENOIDS VIA STEREOSPECIFIC [3,3] SIGMATROPIC REARRANGEMENTS [J].
CHAN, KK ;
COHEN, N ;
DENOBLE, JP ;
SPECIAN, AC ;
SAUCY, G .
JOURNAL OF ORGANIC CHEMISTRY, 1976, 41 (22) :3497-3505
[7]   NOVEL TOTAL SYNTHESIS OF (2R,4'R,8'R)-ALPHA-TOCOPHEROL (VITAMIN-E) - CONSTRUCTION OF CHIRAL CHROMANS FROM AN OPTICALLY-ACTIVE, NON-AROMATIC PRECURSOR [J].
COHEN, N ;
LOPRESTI, RJ ;
SAUCY, G .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (22) :6710-6716
[8]   SYNTHETIC STUDIES ON 2R,4',8'R-ALPHA-TOCOPHEROL - APPROACH UTILIZING SIDE-CHAIN SYNTHONS OF MICROBIOLOGICAL ORIGIN [J].
COHEN, N ;
EICHEL, WF ;
LOPRESTI, RJ ;
NEUKOM, C ;
SAUCY, G .
JOURNAL OF ORGANIC CHEMISTRY, 1976, 41 (22) :3505-3511
[9]  
DANN O, 1954, LIEBIGS ANN CHEM, V587, P16
[10]  
FITTON P, 1978, Patent No. 4208334
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