BIOMIMETIC OXIDATION STUDIES .8. STRUCTURE OF A NEW MMO ACTIVE-SITE MODEL, [FE2O(H2O)2(TRIS(1-METHYLIMIDAZOL-2-YL)METHYL)AMINE)2]4+, AND ROLE OF THE AQUA LIGAND IN ALKANE FUNCTIONALIZATION REACTIONS

被引：79
作者：
BUCHANAN, RM
CHEN, S
RICHARDSON, JF
BRESSAN, M
FORTI, L
MORVILLO, A
FISH, RH
机构：
[1] UNIV MODENA,DIPARTIMENTO CHIM,I-41100 MODENA,ITALY
[2] LAWRENCE BERKELEY LAB,BERKELEY,CA 94720
[3] UNIV PADUA,DIPARTIMENTO CHIM INORGAN,I-35131 PADUA,ITALY
来源：
INORGANIC CHEMISTRY | 1994年 / 33卷 / 15期
关键词：
D O I：
10.1021/ic00093a002
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
[No abstract available]
引用
收藏
页码：3208 / 3209
页数：2
相关论文
共 24 条
[1]   PROTON ENDOR IDENTIFICATION OF BRIDGING HYDROXIDE LIGANDS IN MIXED-VALENT DIIRON CENTERS OF PROTEINS - METHANE MONOOXYGENASE AND SEMIMET AZIDOHEMERYTHRIN [J].
DEROSE, VJ ;
LIU, KE ;
KURTZ, DM ;
HOFFMAN, BM ;
LIPPARD, SJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (14) :6440-6441
[2]   X-RAY ABSORPTION, MOSSBAUER, AND EPR STUDIES OF THE DINUCLEAR IRON CENTER IN THE HYDROXYLASE COMPONENT OF METHANE MONOOXYGENASE [J].
DEWITT, JG ;
BENTSEN, JG ;
ROSENZWEIG, AC ;
HEDMAN, B ;
GREEN, J ;
PILKINGTON, S ;
PAPAEFTHYMIOU, GC ;
DALTON, H ;
HODGSON, KO ;
LIPPARD, SJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (24) :9219-9235
[3]   BIOMIMETIC ORGANOMETALLIC CHEMISTRY - REGIOSELECTIVITY AND STEREOSELECTIVITY IN THE HYDROXYLATION REACTION OF CYCLOHEXYLTRIPHENYLTIN WITH METALLOPORPHYRINS AS THE BIOMIMETIC CATALYSTS AND IODOSYLBENZENE AS THE OXYGEN-TRANSFER AGENT [J].
FISH, RH ;
PRICE, RT .
ORGANOMETALLICS, 1989, 8 (01) :225-228
[4]  
FISH RH, 1992, NEW J CHEM, V16, P727
[5]   BIOMIMETIC OXIDATION STUDIES .5. MECHANISTIC ASPECTS OF ALKANE FUNCTIONALIZATION WITH FE,FE2O, AND FE4O2 COMPLEXES IN THE PRESENCE OF HYDROGEN-PEROXIDE [J].
FISH, RH ;
KONINGS, MS ;
OBERHAUSEN, KJ ;
FONG, RH ;
YU, WM ;
CHRISTOU, G ;
VINCENT, JB ;
COGGIN, DK ;
BUCHANAN, RM .
INORGANIC CHEMISTRY, 1991, 30 (15) :3002-3006
[6]   CARBON HYDROGEN ACTIVATION CHEMISTRY - HYDROXYLATION OF C2, C-3, AND CYCLO-C6 HYDROCARBONS BY MANGANESE CLUSTER CATALYSTS WITH A MONO-OXYGEN TRANSFER REAGENT [J].
FISH, RH ;
FONG, RH ;
VINCENT, JB ;
CHRISTOU, G .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (22) :1504-1506
[7]   BIOMIMETIC OXIDATION STUDIES .7. ALKANE FUNCTIONALIZATION WITH A MMO STRUCTURAL MODEL, [FE2O(OAC)(TRIS((1-METHYLIMIDAZOL-2-YL)METHYL)AMINE)2]3+, IN THE PRESENCE OF T-BUTYL HYDROPEROXIDE AND OXYGEN GAS [J].
FISH, RH ;
OBERHAUSEN, KJ ;
CHEN, S ;
RICHARDSON, JF ;
PIERCE, W ;
BUCHANAN, RM .
CATALYSIS LETTERS, 1993, 18 (04) :357-365
[8]  
FISH RH, 1989, ACS SYM SER, V392, P116
[9]  
FOX BG, 1988, J BIOL CHEM, V263, P10553
[10]   OXO-BRIDGED AND HYDROXO-BRIDGED DIIRON COMPLEXES - A CHEMICAL PERSPECTIVE ON A BIOLOGICAL UNIT [J].
KURTZ, DM .
CHEMICAL REVIEWS, 1990, 90 (04) :585-606
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