INCLUSION-COMPOUNDS IN WATER - CALORIMETRIC AND SPECTROSCOPIC STUDIES OF THE INTERACTION OF CYCLOMALTOHEXAOSE (ALPHA-CYCLODEXTRIN) WITH ALKANOLS AT 25-DEGREES

被引：46

作者：

ANDINI, S ^{[1
]}

CASTRONUOVO, G ^{[1
]}

ELIA, V ^{[1
]}

GALLOTTA, E ^{[1
]}

机构：

[1] UNIV FEDERICO II NAPLES, DEPT CHEM, VIA MEZZOCANNONE 4, I-80134 NAPLES, ITALY

来源：

CARBOHYDRATE RESEARCH | 1991年 / 217卷

关键词：

D O I：

10.1016/0008-6215(91)84119-Y

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

A study of the interaction in water of some alkanols and alkanediols with cyclomaltohexaose (alpha-cyclodextrin, alpha-CD), by calorimetry and H-1-n.m.r. spectroscopy at 25-degrees, indicates that the alkyl chains are included in the cavity of alpha-CD, that 1:1 complexes are formed, and that the formation constants and enthalpies are markedly dependent on the number and position of the hydroxyl groups in the chain. For alpha,omega-alkanediols, the interaction is more complex than a simple inclusion.

引用

页码：87 / 97

页数：11

共 33 条

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