ELECTROSYNTHESIS AND PROPERTIES OF SELF-DOPED POLYANILINE

被引：47
|
作者：
KITANI, A
SATOGUCHI, K
TANG, HQ
ITO, S
SASAKI, K
机构：
[1] Department of Applied Chemistry, Faculty of Engineering, Hiroshima University, Higashi-Hiroshima, 724, Kagamiyama
来源：
SYNTHETIC METALS | 1995年 / 69卷 / 1-3期
关键词：
D O I：
10.1016/0379-6779(94)02387-E
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Sulfonic acid ring-substituted aniline was polymerized electrochemically to obtain self-doped and water soluble polyaniline. The electric conductivity values of polymers derived from three isomers of aminobenzenesulfonic acid were in the order of 10(-3) Scm(-1) for as prepared samples, but increased to 10(-1) similar to 10(-2) Scm(-1) by chemical doping with Fe(III). The conductivity was unchanged by treating with alkaline solutions. These polymers were easily soluble in water and showed fairly reversible redox peak around 0.6 V (vs. SCE).
引用
收藏
页码：129 / 130
页数：2
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