MAGNETIC COUPLING AND H-1-NMR SPECTROSCOPY OF BINUCLEAR COPPER(II) COMPLEXES

被引：46
|
作者：
SATCHER, JH [1 ]
BALCH, AL [1 ]
机构：
[1] UNIV CALIF DAVIS,DEPT CHEM,DAVIS,CA 95616
来源：
INORGANIC CHEMISTRY | 1995年 / 34卷 / 13期
关键词：
D O I：
10.1021/ic00117a001
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
H-1 NMR spectra with narrow, well-resolved resonances are reported for a set of binuclear copper(II) complexes, [Cu-2(L-R)(X)](ClO4)(2). A quantitative relationship exists between the chemical shift of selected peaks and magnetic coupling between the paramagnetic centers over a wide range (2J = +26 to -1100 cm(-1)) of coupling constants. Such spectra are shown to be useful in assaying sample purity and in estimating magnetic coupling constants.
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收藏
页码：3371 / 3373
页数：3
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