(E)-3,4,5-Trimethoxy-N'-[(4-oxo-4H-chromen-3-yl)methylidene]benzo-hydrazide

被引:5
作者
Ishikawa, Yoshinobu [1 ]
Watanabe, Kohzoh [1 ]
机构
[1] Univ Shizuoka, Sch Pharmaceut Sci, Suruga Ku, 52-1 Yada, Shizuoka 4228526, Japan
来源
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷
关键词
single-crystal X-ray study; T = 100 K; mean sigma (C-C) = 0.007 A(degrees); R factor = 0.068; wR factor = 0.208; data-to-parameter ratio = 15.6;
D O I
10.1107/S1600536814005753
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title chromone-tethered benzohydrazide derivative, C 20H18N2O6, the atoms of the E-3-(hydrazonomethyl)-4H-chromen-4-one segment are essentially coplanar, the largest deviation being 0.065(6)Å. The dihedral angle between this segment and the benzene ring of the trimethoxybenzene unit is 40.18(10)Å. In the crystal, the molecule is linked to its inverse-symmetry equivalent by pairs of N-H..O hydrogen bonds and C-H..π interactions. The-CH=N-NH-segment is stacked on the benzene ring of the chromone unit of a translation-related equivalent molecule [centroid-centroid distance = 3.413(6)Å].
引用
收藏
页码:O472 / +
页数:13
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