INERTIAL AND INERTIALESS VIBRATIONAL-MODES IN CHARGE-TRANSFER - A SIMPLE-MODEL

被引：4
作者：
KUZNETSOV, AM
机构：
[1] The A.N. Frumkin Institute of Electrochemistry, the Russian Academy of Sciences, Moscow, 117071
来源：
CHEMICAL PHYSICS | 1992年 / 166卷 / 03期
关键词：
D O I：
10.1016/0301-0104(92)80090-I
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A simple model is considered which allows to find an exact expression for the tunnelling factor of a reaction of light particle transfer in condensed medium without a priori assumption of the relation between the characteristic times of the motion along different degrees of freedom. Two opposite Born-Oppenheimer limits emerge from the exact result as particular cases. Characteristic parameters gouverning the inertial and inertialess behaviour of vibrational degrees of freedom are found.
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页码：303 / 310
页数：8
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