ESR AND OPTICAL STUDIES OF THE RADICAL-ANION OF C60

被引：145

作者：

KATO, T ^{[1
]}

KODAMA, T ^{[1
]}

OYAMA, M ^{[1
]}

OKAZAKI, S ^{[1
]}

SHIDA, T ^{[1
]}

NAKAGAWA, T ^{[1
]}

MATSUI, Y ^{[1
]}

SUZUKI, S ^{[1
]}

SHIROMARU, H ^{[1
]}

YAMAUCHI, K ^{[1
]}

ACHIBA, Y ^{[1
]}

机构：

[1] TOKYO METROPOLITAN UNIV,FAC SCI,DEPT CHEM,HACHIOJI,TOKYO 19203,JAPAN

来源：

CHEMICAL PHYSICS LETTERS | 1991年 / 186卷 / 01期

关键词：

D O I：

10.1016/0009-2614(91)80188-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The ESR and the electronic absorption spectrum of the radical anion of C60 produced by electrolysis were measured at room temperatures and at 77 K. A singlet ESR spectrum with g = 1.999 appeared only at 77 K while the electronic absorption spectrum was observed both at room temperatures and at 77 K. The small value of the g factor was associated with the residual orbital angular momentum. The irregular vibrational structure of the electronic absorption of the radical anion in the frozen matrix band was suggested as being due to the Jahn-Teller distortion.

引用

页码：35 / 39

页数：5

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