DEVELOPMENT OF A VAPOR-PRESSURE EQUATION FOR METHANOL

被引：6

作者：

CRAVEN, RJB

DEREUCK, KM

机构：

[1] IUPAC Thermodynamic Tables Project Centre, Imperial College of Science, Technology and Medicine, London

来源：

FLUID PHASE EQUILIBRIA | 1993年 / 89卷 / 01期

关键词：

VAPOR PRESSURE EQUATION; METHANOL;

D O I：

10.1016/0378-3812(93)85043-L

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

A new vapour pressure equation for methanol is presented which covers the full range from the triple point to the critical point (175-512.6 K). Multiproperty fitting was used which included liquid heat capacity data near the triple point as well as vapour pressure data from around 10 kPa upwards. During the development, two forms of equation were compared; both were fitted to the same set of weighted data using the same selection algorithm to determine the number and value of the coefficients. The final equation required only 4 coefficients to represent the best data to within the experimental accuracy.

引用

页码：19 / 29

页数：11

共 22 条

[1]

Aim K., 1980, J CHEM ENG DATA, V25, P100

[2] THE CORRELATION AND ESTIMATION OF VAPOR-PRESSURES .4. OBSERVATIONS ON WAGNERS METHOD OF FITTING EQUATIONS TO VAPOR-PRESSURES [J].