INTERFACES OF POLYPHENYLENE SULFIDE-TO-METAL JOINTS

被引:20
|
作者
SUGAMA, T
CARCIELLO, NR
机构
[1] Energy Efficiency and Conservation Division, Department of Applied Science, Brookhaven National Laboratory, Upton
关键词
POLYPHENYLENE SULFIDE; STEELS; BOND STRENGTH; INTERFACE; X-RAY PHOTOELECTRON SPECTROSCOPY;
D O I
10.1016/0143-7496(91)90033-E
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
High-temperature polyphenylene sulphide (PPS) film was deposited on the surface of cold-rolled stainless and galvanized steels by slurry coating in N2 and O2 gases at 350-degrees-C The value of the interfacial PPS/steel bond strength depended primarily on the species of sulphur-related iron compounds formed as reaction products at the interfaces. The order of these reaction products, which play an important role in developing bond strength, was Fe2(SO4)3 > FeSO4 > FeS. In contrast, the conversion of ZnS formed at the PPS/galvanized steel interfaces, into ZnSO4 led to a catastrophic loss of bond strength.
引用
收藏
页码:97 / 104
页数:8
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