CLUSTER ION-BEAM STUDY OF A SYSTEM WITH STRUCTURAL ISOMERS - CN++D2 (N = 2-12)

被引：22
作者：
HINTZ, PA
SOWA, MB
ANDERSON, SL
机构：
[1] Department of Chemistry, State University of New York at Stony Brook, Stony Brook
来源：
CHEMICAL PHYSICS LETTERS | 1991年 / 177卷 / 02期
关键词：
D O I：
10.1016/0009-2614(91)90060-M
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
An ion beam study of the reaction of C(n)+ (n = 2-12) with D2 - a system which is known to have reactant structural isomers with very different reactivity - is reported. We give absolute cross sections for the major product channels. By varying collision energy, we can study the chemistry of both reactive and "unreactive" isomers, and we obtain evidence for multiple stable isomers for cluster sizes where thermal energy kinetics work shows only a single component.
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页码：146 / 152
页数：7
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