DYNAMICS OF THE O(3P)+NH2 REACTION - THE HNO+H PRODUCT CHANNEL

被引：11

作者：

PATELMISRA, D

DAGDIGIAN, PJ

机构：

[1] Department of Chemistry, The John Hopkins University, Baltimore

来源：

CHEMICAL PHYSICS LETTERS | 1991年 / 185卷 / 3-4期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0009-2614(91)85080-G

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The internal state distribution of the HNO product from the O(3P) + NH2 reaction was derived in a crossed beam experiment. Rotational state distributions in the K(a) = 0 and 1 manifolds of the ground (000) HNO vibronic level were derived from laser fluorescence excitation spectra. The HNO rotational state distribution was found to be very cold. This reaction product can be formed by decomposition of H2NO and HNOH intermediate. The low degree of energy disposal in HNO internal excitation provides evidence for a barrier (in excess of the endoergicity) for formation of HNO + H from these intermediates, as has been predicted from quantum chemical calculations and a RRK analysis on this reaction.

引用

页码：387 / 392

页数：6

共 29 条

[1] THE CHEMICAL-DYNAMICS OF THE REACTIONS OF O(P-3) WITH SATURATED-HYDROCARBONS .1. EXPERIMENT [J].