The crystal structure of (E)-2-ethyl-N-(4-nitrobenzylidene)aniline: three-dimensional supramolecular assembly mediated by C-H center dot center dot center dot O hydrogen bonds and nitro center dot center dot center dot pi(arene) interactions

被引：1

作者：

Girisha, Marisiddaiah ^{[1
]}

Sagar, Belakavadi K. ^{[1
]}

Yathirajan, Hemmige S. ^{[1
]}

Rathore, Ravindranath S. ^{[2
]}

Glidewell, Christopher ^{[3
]}

机构：

[1] Univ Mysore, Dept Studies Chem, Mysuru 570006, Karnataka, India

[2] Cent Univ South Bihar, Sch Earth Biol & Environm Sci, Ctr Biol Sci Bioinformat, Patna 800014, Bihar, India

[3] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2018年 / 74卷

关键词：

Schiff bases; crystal structure; disorder; molecular conformation; hydrogen bonding; nitro center dot center dot center dot pi(arene) interactions; supra-molecular assembly;

D O I：

10.1107/S2056989018009544

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the molecule of the title compound, C15H14N2O2, the 2-ethylphenyl group is disordered over two sets of atomic sites having occupancies of 0.515 (19) and 0.485 (19), and the dihedral angle between the two partial-occupancy aryl rings is 6(2)degrees. A combination of C-H center dot center dot center dot O hydrogen bonds and nitro center dot center dot center dot pi(arene) interactions links the molecules into a continuous three-dimensional framework structure. Comparisons are made with the structures of some related compounds.

引用

页码：1071 / +

页数：9

共 27 条

[1] 3,4-Dimethoxy-N-(4-nitrobenzylidene)aniline [J].

Akkurt, Mehmet ;

Jarrahpour, Aliasghar ;

Aye, Malihe ;

Gencaslan, Mustafa ;

Bueyuekguengoer, Orhan .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 :O2087-U1643

[2] π-Hole Interactions Involving Nitro Compounds: Directionality of Nitrate Esters [J].

Bauza, Antonio ;

Frontera, Antonio ;

Mooibroek, Tiddo J. .

CRYSTAL GROWTH & DESIGN, 2016, 16 (09) :5520-5524

[3]

Bruker, 2012, APEX2 SAINT SADABS

[4] Schiff bases: A short review of their antimicrobial activities [J].

da Silva, Cleiton M. ;

da Silva, Daniel L. ;

Modolo, Luzia V. ;

Alves, Rosemeire B. ;

de Resende, Maria A. ;

Martins, Cleide V. B. ;

de Fatima, Angelo .

JOURNAL OF ADVANCED RESEARCH, 2011, 2 (01) :1-8

[5] Chain, sheet and framework structures in the adducts of phenylphosphonic acid with 4,4′-bipyridyl (1/1), piperazine (2/1) and 1,4-diazabicyclo[2.2.2]octane (2/1) [J].

Ferguson, G ;

Glidewell, C ;

Gregson, RM ;

Meehan, PR .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1998, 54 :129-138

[6] Crystal engineering using bis- and tris-phenols.: Adducts with 1,4,8,11-tetraazacyclotetradecane (cyclam):: Isolated ladders in the adduct with 4,4′-thiodiphenol, tethered ladders in the adduct with 4,4′-sulfonyldiphenol and two interwoven three-dimensional networks in the adduct with 1,1,1-tris(4-hydroxyphenyl)ethane [J].

Ferguson, G ;

Glidewell, C ;

Gregson, RM ;

Meehan, PR .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1998, 54 :139-150

[7] ON ENANTIOMORPH-POLARITY ESTIMATION [J].

FLACK, HD .

ACTA CRYSTALLOGRAPHICA SECTION A, 1983, 39 (NOV) :876-881

[8] Reinvestigation of the crystal structure of N-(4-chlorobenzylidene)-2-hydroxyaniline: a threedimensional structure containing O-H center dot center dot center dot N, O-H center dot center dot center dot O and C-H center dot center dot center dot pi (arene)hydrogen bonds [J].

Girisha, Marisiddaiah ;

Yathirajan, Hemmige S. ;

Rathore, Ravindranath S. ;

Glidewell, Christopher .

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2018, 74 :376-+

[9]

Girisha M, 2017, ACTA CRYSTALLOGR E, V73, P1835, DOI 10.1107/S2056989017015985

[10] meso-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane as a building block in supramolecular chemistry;: salts formed with 2,2′-biphenol, 4,4′-biphenol, 4,4′-thiodiphenol, 4,4′-sulfonyldiphenol, 3- and 4-hydroxybenzoic acids, 3,5-dihydroxybenzoic acid and phenylphosphonic acid;: supramolecular structures in zero, one, two and three dimensions [J].

Gregson, RM ;

Glidewell, C ;

Ferguson, G ;

Lough, AJ .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 2000, 56 (56) :39-57

← 1 2 3 →