The stereochemistry of organometallic compounds .42. The preparation of [2,1-b]quinazolines involving rhodium-catalysed hydroformylation of 2-amino-N-alkenylbenzylamines

被引：30

作者：

Campi, EM

Habsuda, J

Jackson, WR

Jonasson, CAM

McCubbin, QJ

机构：

[1] Department of Chemistry, Monash University, Clayton

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1995年 / 48卷 / 12期

关键词：

D O I：

10.1071/CH9952023

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Rhodium-catalysed reactions of 2-amino-N-alkenylbenzylamines with H-2/CO give hexahydropyrrolo- and hexahydropyrido-[2,1-b]quinazolines. Reactions of N-allyl derivatives give a single regioisomer, and reactions of but-3-enyl analogues give mixtures of pyrrolo and pyrido derivatives. Some reactions give significant amounts (10-30%) of tetrahydro derivatives. The origin of these compounds remains unclear.

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页码：2023 / 2033

页数：11

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