AN APPROACH TO CHIRAL METAL-CATALYSTS - THE SYNTHESIS AND X-RAY CRYSTAL-STRUCTURES OF A CHIRAL TETRADENTATE BINAPHTHYL BIS-AMIDE LIGAND AND ITS OSMIUM(VI)-OXO DERIVATIVE

被引：31

作者：

LIN, JH ^{[1
]}

CHE, CM ^{[1
]}

LAI, TF ^{[1
]}

POON, CK ^{[1
]}

CUI, YX ^{[1
]}

机构：

[1] UNIV HONG KONG,DEPT CHEM,POKFULAM RD,HONG KONG,HONG KONG

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 07期

关键词：

D O I：

10.1039/c39910000468

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis, X-ray crystal structures and resolution of a chiral tetradentate binaphthyl bis-amide ligand and its osmium(VI)-oxo derivative are described.

引用

页码：468 / 470

页数：3

共 17 条

[1]

BROWN JM, 1989, CHEM BRIT, V25, P276

[2] HIGH-VALENT OXO COMPLEXES OF OSMIUM AS SELECTIVE OXIDANTS FOR CYCLOHEXENE OXIDATION - COMPLEXATION OF THE BISAMIDE TETRADENTATE LIGAND BPB TO OSMIUM AND THE X-RAY STRUCTURE OF TRANS-[OSIII(BPB)(PPH3)CL] [BPBH2=N,N'-BIS(2'-PYRIDINE-CARBOXAMIDE)-1,2-BENZENE] [J].

CHE, CM ;

CHENG, WK ;

MAK, TCW .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (03) :200-202

[3] MANGANESE(III) AMIDE COMPLEXES AS A NEW CLASS OF CATALYST FOR EFFICIENT ALKENE EPOXIDATION [J].

CHE, CM ;

CHENG, WK .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (18) :1443-1444

[4] SYNTHESIS, REACTIVITY, AND X-RAY STRUCTURAL CHARACTERIZATION OF TRANS-DIOXOOSMIUM(VI) PORPHYRIN COMPLEXES [J].

CHE, CM ;

CHUNG, WC ;

LAI, TF .

INORGANIC CHEMISTRY, 1988, 27 (16) :2801-2804

[5] SYNTHESIS AND REACTIVITIES OF TRANS-DIOXOOSMIUM(VI) SCHIFF-BASE COMPLEXES - X-RAY CRYSTAL-STRUCTURE OF DIOXO[N,N'-(1,1,2,2-TETRAMETHYLETHYLENE)BIS(3-TERT-BUTYLSALICYLIDENAMINATO)]OSMIUM(VI) [J].

CHE, CM ;

CHENG, WK ;

MAK, TCW .

INORGANIC CHEMISTRY, 1988, 27 (02) :250-253

[6]

CHE CM, IN PRESS

[7] ALKYNE ADDITION-REACTIONS ON PENTAAMMINEOSMIUM(II) - THE FORMATION OF PI-ENOL AND PI-VINYL ETHER COMPLEXES [J].

HARMAN, WD ;

DOBSON, JC ;

TAUBE, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (08) :3061-3062

[8]

HARMAN WD, 1990, J AM CHEM SOC, V112, P1682

[9] ASYMMETRIC DIHYDROXYLATION VIA LIGAND-ACCELERATED CATALYSIS [J].

JACOBSEN, EN ;

MARKO, I ;

MUNGALL, WS ;

SCHRODER, G ;

SHARPLESS, KB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (06) :1968-1970

[10] THE 1ST PRACTICAL METHOD FOR ASYMMETRIC EPOXIDATION [J].

KATSUKI, T ;

SHARPLESS, KB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (18) :5974-5976

← 1 2 →