FLUOROSULFURIC ACID SOLVENT SYSTEM .6. SOLUTIONS OF PHOSPHORUS ARSENIC BISMUTH AND NIOBIUM PENTAFLUORIDES AND TITANIUM TETRAFLUORIDE

被引：31
作者：
GILLESPIE, RJ
OUCHI, K
PEZ, GP
机构：
[1] Department of Chemistry, McMaster University, Hamilton, Ontario
来源：
INORGANIC CHEMISTRY | 1969年 / 8卷 / 01期
关键词：
D O I：
10.1021/ic50071a015
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Conductivity measurements on solutions of PF5, AsF5, BiF5, NbF5, PF5-SO3, NbF5-SO3, and AsF5·SO3 are reported. Conductometric titrations have been carried out on solutions of AsF5, BiF5, and AsF5-SO3. The results are compared with those obtained previously for SbFs and SbF5-S03. It is concluded that acid strength increases in the order: PF5 ~NbF5 < TiF4 ~ AsF5 < BiF5 < AsF4(SO3F) < SbF6 < AsF2(SO3F)3 < SbF2(SO3F)3. © 1969, American Chemical Society. All rights reserved.
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页码：63 / +
页数：1
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