STRUCTURAL STUDIES ON POLYNUCLEAR OSMIUM CARBONYL HYDRIDES .1. CRYSTAL-STRUCTURES OF ISOMORPHOUS SPECIES H2OS3(CO)11 AND OS3(CO)12 - DIRECT INFORMATION ON ROLE OF AN EQUATORIAL MU-2-BRIDGING HYDRIDE LIGAND IN PERTURBING ARRANGEMENT OF CARBONYL LIGANDS IN A TRIANGULAR CLUSTER

被引：575
作者：
CHURCHILL, MR
DEBOER, BG
机构：
[1] SUNY BUFFALO,DEPT CHEM,BUFFALO,NY 14214
[2] UNIV ILLINOIS,DEPT CHEM,CHICAGO,IL 60680
来源：
INORGANIC CHEMISTRY | 1977年 / 16卷 / 04期
关键词：
D O I：
10.1021/ic50170a032
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
引用
收藏
页码：878 / 884
页数：7
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[1]   PREPARATION AND CRYSTALLOGRAPHIC CHARACTERIZATION OF A HEXAMERIC TRIPHENYLPHOSPHINECOPPER HYDRIDE CLUSTER [J].
BEZMAN, SA ;
CHURCHIL.MR ;
OSBORN, JA ;
WORMALD, J .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (08) :2063-&
[2]   CRYSTAL STRUCTURE OF ZIRCONIUM (4) BOROHYDRIDE (AT-160 DEGREES) [J].
BIRD, PH ;
CHURCHILL, MR .
CHEMICAL COMMUNICATIONS, 1967, (08) :403-+
[3]   CRYSTAL AND MOLECULAR-STRUCTURE OF 1,6,7,8-TETRAHAPTOHEPTAFULVENEIRON TRICARBONYL, A HEPTAFULVENE COMPLEX OF IRON(O) CONTAINING A TRIMETHYLENEMETHANE-IRON LINKAGE [J].
CHURCHILL, MR ;
DEBOER, BG .
INORGANIC CHEMISTRY, 1973, 12 (03) :525-531
[4]   CRYSTAL-STRUCTURE AND MOLECULAR-GEOMETRY OF HRU3(CO)10(C=NME2), INCLUDING DIRECT LOCATION OF MU-2-BRIDGING HYDRIDE LIGAND [J].
CHURCHILL, MR ;
DEBOER, BG ;
ROTELLA, FJ .
INORGANIC CHEMISTRY, 1976, 15 (08) :1843-1853
[5]   CHARACTERIZATION OF AN ANIONIC RHENIUM CARBONYL HYDRIDE [H2RE3(CO)12-] [J].
CHURCHILL, MR ;
BIRD, PH ;
KAESZ, HD ;
BAU, R ;
FONTAL, B .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (25) :7135-+
[6]   X-RAY CRYSTALLOGRAPHIC DETERMINATION OF MOLECULAR-STRUCTURE OF BIS(TETRAETHYLAMMONIUM) DI-MU-HYDRIDO-OCTACARBONYLDITUNGSTATE(2-), [ET4N+]2[H2W2(CO)82-] - UNIQUE EXAMPLE OF SUCCESSFUL LOCATION AND REFINEMENT OF HYDRIDE LIGANDS IN POSITIONS BRIDGING THIRD-ROW TRANSITION-METAL ATOMS [J].
CHURCHILL, MR ;
CHANG, SWY .
INORGANIC CHEMISTRY, 1974, 13 (10) :2413-2419
[7]   CRYSTAL STRUCTURE OFA TRINUCLEAR TRANSITION METAL CARBONYL HYDRIDE - HRE2MN(CO)14 [J].
CHURCHILL, MR ;
BAU, R .
INORGANIC CHEMISTRY, 1967, 6 (11) :2086-+
[8]   CRYSTAL STRUCTURE AND MOLECULA GEOMETRY OF OCTADECACARBONYLHEXARUTHENIUM DIHYDRIDE [J].
CHURCHILL, MR ;
WORMALD, J .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (22) :5670-+
[9]   SYNTHESIS AND MOLECULAR GEOMETRY OF HEXAMERIC TRIPHENYLPHOSPHINOCOPPER(I) HYDRIDE AND CRYSTAL-STRUCTURE OF H6CU6(PPH3)6.HCONME2 [J].
CHURCHILL, MR ;
BEZMAN, SA ;
OSBORN, JA ;
WORMALD, J .
INORGANIC CHEMISTRY, 1972, 11 (08) :1818-+
[10]   ATTACK BY PHOSPHORUS NUCLEOPHILES ON A CLUSTER-BOUND VINYL GROUP - CRYSTAL-STRUCTURE OF HOS-3(CO)10(CHCH-2PME-2PH) [J].
CHURCHILL, MR ;
DEBOER, BG ;
SHAPLEY, JR ;
KEISTER, JB .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (08) :2357-2358
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