MATHEMATICAL SIMULATION OF THE RADIATION-CHEMICAL PROCESSES IN HCLO4 SOLUTIONS

被引：0
|
作者：
VLADIMIROVA, MV
机构：
来源：
HIGH ENERGY CHEMISTRY | 1995年 / 29卷 / 05期
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中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The mathematical simulation of the radiolysis of aqueous solutions of HClO4 (0.5 - 12 mol/l) under X-ray irradiation was performed. An optimal scheme of radiation-chemical reactions was adopted. It was demonstrated that the calculated and experimental yields of ClO3- ions are in good agreement if the yield of ClO3- formation by a direct-action mechanism is taken equal to 3.2 ion/100 eV. By comparing the calculated and experimental yields and the rate curves of ClO2 and Cl- formation, the reaction rate constants of HO2 radicals with ClO2- and ClO2 and of ClO radicals with H2O2 were found.
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页码：304 / 309
页数：6
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