HIGHLY EFFICIENT CARBONYL ALLYLATION OF 1,3-DICARBONYL COMPOUNDS IN AQUEOUS-MEDIUM

被引：45
作者：
LI, CJ
LU, YQ
机构：
[1] Department of Chemistry, Tulane University, New Orleans
来源：
TETRAHEDRON LETTERS | 1995年 / 36卷 / 16期
关键词：
D O I：
10.1016/0040-4039(95)00377-O
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Beta-keto esters undergo efficient carbonyl allylation reactions in aqueous medium through a Barbier-type reaction. The reaction is general and a variety of 1,3-dicarbonyl compounds have been alkylated successfully using allyl bromide or allyl chloride in conjunction with either tin or indium.
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页码：2721 / 2724
页数：4
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