24-BETA-METHYL-5-ALPHA-CHOLEST-9(11)-EN-3-BETA-OL, 2 24-BETA-ALKYL-DELTA-5,7,9(11)-STEROLS AND OTHER 24-BETA-ALKYLSTEROLS FROM CHLORELLA-VULGARIS

被引:20
作者
AKIHISA, T
HORI, T
SUZUKI, H
SAKOH, T
YOKOTA, T
TAMURA, T
机构
[1] CHLORELLA IND CO,MINATO KU,TOKYO 105,JAPAN
[2] TEIKYO UNIV,SCH SCI & ENGN,DEPT BIOSCI,UTSUNOMIYA,TOCHIGI 320,JAPAN
关键词
CHLORELLA-VULGARIS; CHLOROPHYCEAE; GREEN ALGA; STEROLS; 24-BETA-METHYL-5-ALPHA-CHOLEST-9(11)-EN-3-BETA-OL; 9(11)-DEHYDROERGOSTEROL; 24-BETA-ETHYLCHOLESTA-5,7,9(11),22E-TETRAEN-3-BETA-OL; ERGOSTEROL; 7-DEHYDROPORIFERASTEROL;
D O I
10.1016/0031-9422(92)83144-N
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Two 24-beta-alkyl-DELTA-5,7-sterols, ergosterol (51% of the sterol mixture) and 7-dehydroporiferasterol (30%), were the principal sterols of Chlorella vulgaris. In addition two 24-beta-methyl-DELTA-9(11)-sterols, 24-beta-methyl-5-alpha-cholest-9(11)-en-3-beta-ol and 14-alpha,24-beta-dimethyl-5-alpha-cholest-9(11)-en-3-beta-ol, and two 24-beta-alkyl-DELTA-5,7,9(11)-sterols, 9(11)-dehydroergosterol and 24-beta-ethylcholesta-5,7,9(11),22E-tetraen-3-beta-ol, were isolated and identified from among the other DELTA-5- and DELTA-7-sterols. This is the first report of the natural occurrence of 24-beta-methyl-5-alpha-cholest-9(11)-en-3-beta-ol as well as the first report of the detection of 24-beta-ethylcholesta-5,7,9(11),22E-tetraen-3-beta-ol in an alga.
引用
收藏
页码:1769 / 1772
页数:4
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