[1H-1,2,4-Triazole-5(4H)-thione-kappa S]bis(triphenylphosphane-kappa P)(nitrato-kappa O)silver(I) methanol monosolvate

被引：3

作者：

Wattanakanjana, Yupa ^{[1
]}

Palamae, Sureeporn ^{[1
]}

Ratthiwan, Jenejira ^{[1
]}

Nimthong, Ruthairat ^{[1
]}

机构：

[1] Prince Songkla Univ, Fac Sci, Dept Chem, Hat Yai 90112, Songkhla, Thailand

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷

关键词：

data-to-parameter ratio = 23.4; mean σ(C-C) = 0.003 Å; R factor = 0.041; single-crystal X-ray study; T = 100 K; wR factor = 0.100;

D O I：

10.1107/S1600536814001196

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title complex, [Ag(NO3)(C2H3N3S)(C18H15P)(2)]center dot CH3OH, the Ag I ion exhibits a distorted tetrahedral coordination geometry formed by two P atoms from two triphenylphosphine ligands, one S atom from a 1H-1,2,4triazole-5(4H)-thione ligand and one O atom from a nitrate ion. In the crystal, complex and solvent molecules are linked by O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonds forming a chain along the b-axis direction. The chains are linked by weak C-H center dot center dot center dot O hydrogen bonds forming a two- dimensional supramolecular architecture parallel to (001). In addition, an intramolecular N-H center dot center dot center dot O hydrogen bond is observed.

引用

页码：M61 / +

页数：13

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