MAGNETIC, SPECTRAL AND THERMAL INVESTIGATIONS OF LANTHANIDE(III) NITRATO AND ISOTHIOCYANATO COMPLEXES OF 4-[(N-4-HYDROXY-3-METHOXYBENZALIDENE)AMINO]-ANTIPYRINE

被引：3
作者：
AGARWAL, RK
SARIN, RK
机构：
[1] Department of Chemistry, Lajpat Rai (P.G.) College (Meerut University)
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1994年 / 24卷 / 04期
关键词：
D O I：
10.1080/00945719408000128
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The coordination complexes of 4-[(N-4-hydroxy-3-methoxybenzalidene)amino]antipyrine (HMBAAP) with Ln(NO3)3 and Ln(NCS)3 (Ln = La, Pr, Nd, Sm, Gd, Tb or Dy) have been synthesized. The elemental analyses, infrared and electronic spectra, molar conductance and thermogravimetric data show that the ligand coordinates with a molar ratio of either 2:1 or 3:1. The complexes are non-electrolytes in nitrobenzene and are more thermostable than the ligand.
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页码：499 / 517
页数：19
相关论文
共 27 条
[11]   ENVIRONMENTAL EFFECTS ON F-F TRANSITIONS .2. HYPERSENSITIVITY IN SOME COMPLEXES OF TRIVALENT NEODYMIUM [J].
HENRIE, DE ;
CHOPPIN, GR .
JOURNAL OF CHEMICAL PHYSICS, 1968, 49 (02) :477-&
[12]  
JORGENSEN CK, 1964, Z NATURFORSCH PT A, VA 19, P424
[13]   METAL NITRATE AND THIOCYANATE COMPLEXES WITH 2,6-LUTIDINE N-OXIDE [J].
KARAYANNIS, NM ;
LABES, MM ;
MIKULSKI, CM ;
PYTLEWSKI, LL .
JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1972, 34 (10) :3139-+
[14]  
KOPPIKAR DK, 1978, STRUCT BOND, V34, P165
[15]  
KRISHNAMURTHY SS, 1966, CURR SCI INDIA, V35, P389
[16]  
Lever A. B. P., 1971, Canadian Journal of Chemistry, V49, P1957, DOI 10.1139/v71-315
[17]  
MITCHELL PCH, 1960, J CHEM SOC, V1912
[18]  
Nakamoto K., 1970, INFRARED SPECTRA INO
[19]   COMPLEXES OF LANTHANIDE NITRATES WITH 4N-(2'-HYDROXY BENZYLIDENE)-AMINOANTIPYRINE [J].
RADHAKRISHNAN, PK ;
INDRASENAN, P ;
NAIR, CGR .
POLYHEDRON, 1984, 3 (01) :67-70
[20]   COMPLEXES OF LANTHANIDE PERCHLORATES WITH 4-N-(2'-HYDROXY-1'-NAPHTHYLIDENE)AMINOANTIPYRINE [J].
RADHAKRISHNAN, PK .
POLYHEDRON, 1986, 5 (04) :995-998
123