MAGNETIC, SPECTRAL AND THERMAL INVESTIGATIONS OF LANTHANIDE(III) NITRATO AND ISOTHIOCYANATO COMPLEXES OF 4-[(N-4-HYDROXY-3-METHOXYBENZALIDENE)AMINO]-ANTIPYRINE

被引：3

作者：

AGARWAL, RK

SARIN, RK

机构：

[1] Department of Chemistry, Lajpat Rai (P.G.) College (Meerut University)

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1994年 / 24卷 / 04期

关键词：

D O I：

10.1080/00945719408000128

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The coordination complexes of 4-[(N-4-hydroxy-3-methoxybenzalidene)amino]antipyrine (HMBAAP) with Ln(NO3)3 and Ln(NCS)3 (Ln = La, Pr, Nd, Sm, Gd, Tb or Dy) have been synthesized. The elemental analyses, infrared and electronic spectra, molar conductance and thermogravimetric data show that the ligand coordinates with a molar ratio of either 2:1 or 3:1. The complexes are non-electrolytes in nitrobenzene and are more thermostable than the ligand.

引用

页码：499 / 517

页数：19

共 27 条

[1]

AGARWAL RK, 1987, POL J CHEM, V61, P341

[2] PHOSPHINE OXIDE COMPLEXES OF ACTINIDE(IV) THIOCYANATES [J].