GENERATION OF ALPHA-SULFONYLVINYLITHIUM REAGENTS BY THE LITHIATION OF VINYLIC SULFONES

被引：104
作者：
EISCH, JJ
GALLE, JE
机构：
[1] Department of Chemistry, State University of New York at Binghamton, Binghamton
来源：
JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 18期
关键词：
D O I：
10.1021/jo01332a045
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Methyllithium lithiates phenyl vinylic sulfones at -95°C in THF solution to yield a-(phenylsulfonyl)- vinyllithium reagents. © 1979, American Chemical Society. All rights reserved.
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页码：3279 / 3280
页数：2
相关论文
共 19 条
[1]   CHLORINE-ACTIVATION BY REDOX-TRANSFER .4. ADDITION OF SULPHONYL CHLORIDES TO VINYLIC MONOMERS + OTHER OLEFINS [J].
ASSCHER, M ;
VOFSI, D .
JOURNAL OF THE CHEMICAL SOCIETY, 1964, (DEC) :4962-&
[2]  
BIELLMANN JF, 1978, TETRAHEDRON LETT, P467
[3]  
Block E., 1978, REACTIONS ORGANOSULF
[4]  
CHASSAING G, 1978, TETRAHEDRON LETT, P471
[5]  
EISCH JJ, 1979, ADV CHEM SER, P195
[6]   NOVEL CYCLIZATION OF 1-(ALKYL-THIO OR PHENYL-THIO)-4-(METHYLTHIO)BUTA-1,3-DIENES TO THIOPHENE DERIVATIVES [J].
EVERHARDUS, RH ;
EEUWHORST, HG ;
BRANDSMA, L .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1977, (22) :801-802
[7]   FACILE REDUCTION OF SULFONES TO SULFIDES [J].
GARDNER, JN ;
KAISER, S ;
KRUBINER, A ;
LUCAS, H .
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1973, 51 (09) :1419-1421
[8]   TOTAL SYNTHESIS OF BIOTIN BASED ON STEREOSELECTIVE ALKYLATION OF SULFOXIDES [J].
LAVIELLE, S ;
BORY, S ;
MOREAU, B ;
LUCHE, MJ ;
MARQUET, A .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (05) :1558-1563
[9]   RECENT DEVELOPMENTS IN SULFONE CHEMISTRY [J].
MAGNUS, PD .
TETRAHEDRON, 1977, 33 (16) :2019-2045
[10]   NEW SYNTHESIS OF KETONES USING 1-(ALKYLTHIO)VINYLLITHIUM [J].
OSHIMA, K ;
SHIMOJI, K ;
TAKAHASH.H ;
YAMAMOTO, H ;
NOZAKI, H .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (08) :2694-2695
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