HYDROGEN PHOTOGENERATION FROM AQUEOUS-SOLUTIONS OF ALCOHOLS BY THE FE3+ ION

被引：3
作者：
TENNAKONE, K
KETIPEARACHCHI, US
ILEPERUMA, OA
PUNCHIHEWA, S
机构：
[1] UNIV RUHUNA,DEPT PHYS,MATERA,SRI LANKA
[2] UNIV PERADENIYA,DEPT CHEM,PERADENIYA,SRI LANKA
来源：
JOURNAL OF MOLECULAR CATALYSIS | 1991年 / 64卷 / 02期
关键词：
D O I：
10.1016/0304-5102(91)85107-D
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Fe(III) chlorocomplex ions are found to generate hydrogen from aqueous solutions of aliphatic alcohols on photolysis with a medium pressure Hg lamp. The reaction mechanism is believed to involve the formation of reactive intermediates Cl. and H., where H. abstracts hydrogen from the alcohol.
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页码：155 / 162
页数：8
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