PROP-2-YNYL ALCOHOL AS A PRECURSOR TO THE ETA(1)-ETHENYL LIGAND

被引：31

作者：

OCONNOR, JM

HIIBNER, K

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 12期

关键词：

D O I：

10.1039/c39950001209

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the presence of water the unsaturated iridium (III) metallacyclopentadiene halide complex Ir(CR=CRCR=CR)(PPh(3))(2)Cl (1, R = CO(2)Me) undergoes reaction with prop-2-ynyl alcohol, or methyl prop-2-ynyl ether at room temperature to give the eta(1)-ethenyl complex Ir(CR=CRCR=CR)(PPh(3))2(CO)(eta(1)-CH=CH2) (3, R = CO(2)Me) in quantitative yield.

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页码：1209 / 1210

页数：2

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